Synthesis of nickel nanoparticles and carbon encapsulated nickel nanoparticles supported on carbon nanotubes

被引:82
作者
Cheng, JP [1 ]
Zhang, XB
Ye, Y
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 210027, Peoples R China
[2] Zhejiang Univ, Dept Earth Sci, Hangzhou 310027, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon nanotube; nickel nanoparticles; microstructure; carbon encapsulation; magnetic property;
D O I
10.1016/j.jssc.2005.10.001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nickel nanoparticles were prepared and uniformly supported on multi-walled carbon nanotubes (MWCNTs) by reduction route with CNTs as a reducing agent at 600 degrees C. As-prepared nickel nanoparticles were single crystalline with a face-center-cubic phase and a size distribution ranging from 10 to 50 nm, and they were characterized by transmission electron microscopy (TEM), high-resolution TEM and X-ray diffraction (XRD). These nickel nanoparticles would be coated with graphene layers. when they were exposed to acetylene at 600 degrees C. The coercivity values of nickel nanoparticles were superior to that of bull, nickel at room temperature. (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码:91 / 95
页数:5
相关论文
共 28 条
[1]   Carbons as supports for industrial precious metal catalysts [J].
Auer, E ;
Freund, A ;
Pietsch, J ;
Tacke, T .
APPLIED CATALYSIS A-GENERAL, 1998, 173 (02) :259-271
[2]   Carbon nanotube synthesis and parametric study using CaCO3 nanocrystals as catalyst support by CVD [J].
Cheng, JP ;
Zhang, XB ;
Luo, ZQ ;
Liu, F ;
Ye, Y ;
Yin, WZ ;
Liu, W ;
Han, YX .
MATERIALS CHEMISTRY AND PHYSICS, 2006, 95 (01) :5-11
[3]   Synthesis of carbon nanotubes filled with Fe3C nanowires by CVD with titanate modified palygorskite as catalyst [J].
Cheng, JP ;
Zhang, XB ;
Liu, F ;
Tu, JP ;
Ye, Y ;
Ji, YJ ;
Chen, CP .
CARBON, 2003, 41 (10) :1965-1970
[4]  
Cullity BD, 1978, ELEMENTS XRAY DIFFRA
[5]   CONTROLLED-SIZE NANOCAPSULES [J].
DRAVID, VP ;
HOST, JJ ;
TENG, MH ;
ELLIOT, B ;
HWANG, JH ;
JOHNSON, DL ;
MASON, TO ;
WEERTMAN, JR .
NATURE, 1995, 374 (6523) :602-602
[6]   CAPILLARITY AND WETTING OF CARBON NANOTUBES [J].
DUJARDIN, E ;
EBBESEN, TW ;
HIURA, H ;
TANIGAKI, K .
SCIENCE, 1994, 265 (5180) :1850-1852
[7]   Decoration of carbon nanotubes [J].
Ebbesen, TW ;
Hiura, H ;
Bisher, ME ;
Treacy, MMJ ;
ShreeveKeyer, JL ;
Haushalter, RC .
ADVANCED MATERIALS, 1996, 8 (02) :155-&
[8]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[9]   Modified carbon nanotubes: an effective way to selective attachment of gold nanoparticles [J].
Jiang, LQ ;
Gao, L .
CARBON, 2003, 41 (15) :2923-2929
[10]   Single-walled tubes and encapsulated nanoparticles: comparison of structural properties of carbon nanoclusters prepared by three different methods [J].
Jiao, J ;
Seraphin, S .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2000, 61 (07) :1055-1067