The role of metal-oxygen intermediates in biological and chemical monooxygenation of alkanes

被引：25

作者：

Shteinman, AA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 10期

关键词：

cytochrome P450; methane monooxygenase; mechanism; metal-oxygen intermediates; monooxygenation of alkanes; hydroxylation of alkanes; biomimetic catalysis; ferryl; oxygen transfer; iron complexes;

D O I：

10.1023/A:1014321827168

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The role of metal-peroxo, -hydroperoxo, and -oxo intermediates in activation Of O-2 and transfer of an oxygen atom to the C-H bond in biocatalysis by heme and non-heme monooxygenases and biomimetic oxidation of alkanes is reviewed.

引用

页码：1795 / 1810

页数：16

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