A note on isotopic ratios and the global atmospheric methane budget

被引:75
作者
Tans, PP
机构
[1] Climate Monitoring/Diagnostics Lab., Natl. Oceanic/Atmosph. Adminstration, Boulder, CO
[2] Climate Monitoring/Diagnostics Lab., Natl. Oceanic/Atmosph. Adminstration, Mail Code R/E/CG1, Boulder, CO 80303
关键词
D O I
10.1029/96GB03940
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The temporal and spatial behavior of the isotopic ratio of atmospheric methane can be quite different from that of total methane. Changes in the isotopic ratio are the result of shifts between isotopically different methane sources, as well as changes in the total amount of methane into which methane from sources is being diluted. As a result, the timescale for isotopic changes is often considerably longer than for changes in total methane, and large-scale spatial gradients of the isotopic ratio adjust very slowly to a new source configuration, in sharp contrast to total methane.
引用
收藏
页码:77 / 81
页数:5
相关论文
共 11 条
[2]   CARBON KINETIC ISOTOPE EFFECT IN THE OXIDATION OF METHANE BY THE HYDROXYL RADICAL [J].
CANTRELL, CA ;
SHETTER, RE ;
MCDANIEL, AH ;
CALVERT, JG ;
DAVIDSON, JA ;
LOWE, DC ;
TYLER, SC ;
CICERONE, RJ ;
GREENBERG, JP .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1990, 95 (D13) :22455-22462
[3]   BIOGEOCHEMICAL ASPECTS OF ATMOSPHERIC METHANE [J].
Cicerone, R. ;
Oremland, R. .
GLOBAL BIOGEOCHEMICAL CYCLES, 1988, 2 (04) :299-327
[4]   THE ISOTOPIC COMPOSITION OF METHANE IN POLAR ICE CORES [J].
CRAIG, H ;
CHOU, CC ;
WELHAN, JA ;
STEVENS, CM ;
ENGELKEMEIR, A .
SCIENCE, 1988, 242 (4885) :1535-1539
[5]   RATE-CONSTANT RATIO FOR THE REACTIONS OF OH WITH CH3D AND CH4 [J].
DEMORE, WB .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (33) :8564-8566
[6]   3-DIMENSIONAL MODEL SYNTHESIS OF THE GLOBAL METHANE CYCLE [J].
FUNG, I ;
JOHN, J ;
LERNER, J ;
MATTHEWS, E ;
PRATHER, M ;
STEELE, LP ;
FRASER, PJ .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1991, 96 (D7) :13033-13065
[7]  
HEIN R, 1997, IN PRESS GLOBAL BIOG
[8]   ATMOSPHERIC METHANE AND ITS CARBON ISOTOPES IN THE SOUTHERN-HEMISPHERE - THEIR TIME-SERIES AND AN INSTRUCTIVE MODEL [J].
LASSEY, KR ;
LOWE, DC ;
BRENNINKMEIJER, CAM ;
GOMEZ, AJ .
CHEMOSPHERE, 1993, 26 (1-4) :95-109
[9]   CARBON ISOTOPIC COMPOSITION OF ATMOSPHERIC CH4: FOSSIL AND BIOMASS BURNING SOURCE STRENGTHS [J].
Quay, P. D. ;
King, S. L. ;
Stutsman, J. ;
Wilbur, D. O. ;
Steele, L. P. ;
Fung, I. ;
Gammon, R. H. ;
Brown, T. A. ;
Farwell, G. W. ;
Grootes, P. M. ;
Schmidt, F. H. .
GLOBAL BIOGEOCHEMICAL CYCLES, 1991, 5 (01) :25-47