Excess molar volumes and viscosities of binary mixtures of 4-methylpyridine with methanol, ethanol, propan-1-ol, propan-2-ol, butan-2-ol, and 2-methylpropan-2-ol at 298.15 K and atmospheric pressure

被引:21
作者
Haraschta, P [1 ]
Heintz, A [1 ]
Lehmann, JK [1 ]
Peters, A [1 ]
机构
[1] Univ Rostock, Dept Phys Chem, D-18051 Rostock, Germany
关键词
D O I
10.1021/je990086f
中图分类号
O414.1 [热力学];
学科分类号
摘要
New experimental data on densities and viscosities for the systems 4-methylpyridine + methanol, + ethanol, + propan-1-ol, + propan-2-ol, + butan-2-ol, and + 2-methylpropan-2-ol are presented at 298.15 K and ambient pressure using a vibrating tube densimeter and an Ubbelohde viscometer. The results are discussed qualitatively in terms of the association of the mixture components caused by chainlike self-association of the alcohol molecules and cross-association between alcohol and 4-methylpyridine.
引用
收藏
页码:932 / 935
页数:4
相关论文
共 30 条
[1]  
*ANT PAAR GMBH, OP INSTR DMA 602
[2]   THERMODYNAMICS OF THE TERNARY MIXTURE PROPAN-1-OL + TRIETHYLAMINE + NORMAL-HEPTANE - EXPERIMENTAL RESULTS AND ERAS-MODEL CALCULATIONS OF HE AND VE [J].
BENDER, M ;
HAUSER, J ;
HEINTZ, A .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1991, 95 (07) :801-811
[3]  
BENDER M, 1993, FLUID PHASE EQUILIBR, V89, P241
[4]   EXCESS VOLUMES AND EXCESS VISCOSITIES OF BINARY-MIXTURES OF CYCLOHEXANE PLUS PICOLINE [J].
BLASCO, D ;
LAFUENTE, C ;
SANTAFE, J ;
ROYO, FM ;
URIETA, JS .
THERMOCHIMICA ACTA, 1993, 230 :55-63
[5]   Dynamic viscosities of (methyl acetate or methanol) with (ethanol, 1-propanol, 2-propanol, 1-butanol, and 2-butanol) at 298.15K [J].
Canosa, J ;
Rodriguez, A ;
Tojo, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1998, 43 (03) :417-421
[6]   Excess volumes and excess viscosities of binary mixtures of 2-chlorobutane with isomeric butanols at 298.15 K [J].
Cea, P ;
Lafuente, C ;
Morand, JP ;
Royo, FM ;
Urieta, JS .
PHYSICS AND CHEMISTRY OF LIQUIDS, 1995, 29 (02) :69-77
[7]   EXPERIMENTAL AND THEORETICAL-STUDY OF THE APPARENT MOLAR VOLUMES OF 1-ALCOHOLS IN LINEAR HYDROCARBONS [J].
COSTAS, M ;
ALONSO, MC ;
HEINTZ, A .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1987, 91 (03) :184-190
[8]   TOPOLOGICAL INVESTIGATIONS ON THE ASSOCIATION OF ALKANOLS - EXCESS VOLUME OF PYRIDINE-ALKANOL (C1-C10) MIXTURES [J].
DEWAN, RK ;
MEHTA, SK ;
PARASHAR, R ;
BALA, K .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (10) :1561-1568
[9]   NEW APPLICATIONS OF THE ERAS MODEL - THERMODYNAMICS OF AMINE+ALKANE AND ALCOHOL+AMINE MIXTURES [J].
FUNKE, H ;
WETZEL, M ;
HEINTZ, A .
PURE AND APPLIED CHEMISTRY, 1989, 61 (08) :1429-1439
[10]   Mixing properties of the liquid systems methanol plus 2-propanol and 1-propanol plus 2-propanol [J].
Haase, R ;
Tillmann, W .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1995, 192 :121-131