Biaryl phosphane ligands in palladium-catalyzed amination

被引：1804

作者：

Surry, David S. ^{[1
]}

Buchwald, Stephen L. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 34期

基金：

美国国家卫生研究院;

关键词：

coupling reactions; heterocycles; homogeneous catalysis; palladium; phophane ligands;

D O I：

10.1002/anie.200800497

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses the application of these catalysts in C-N cross-coupling reactions in the synthesis of heterocycles and pharmaceuticals, in materials science, and in natural product synthesis. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：6338 / 6361

页数：24

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