Dyes derived from aminothiophenes .2. Spectrosceptic properties of some disperse dyes derived from 2-aminothiophenes

被引:15
作者
Hallas, G
Towns, AD
机构
[1] Dept. of Colour Chemistry and Dyeing, University of Leeds, Leeds
关键词
aminothiophenes; heterocyclic azo dyes; PPP-MO calculations; solvatochromism; halochromism;
D O I
10.1016/S0143-7208(96)00047-2
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The colour properties of a series of ren to violet thienyl-2-azo disperse dyes in solution have been investigated. As expected, the attachment of increasingly electron-withdrawing groups to the thiophene ring resulted in bathocromic and hyperchromic shifts, The shifts in absorption maxima were predicted quantitatively by PPP-MO calculations with reasonable accuracy. The solvatochromism and halochromic behaviour of the dyes were also examined. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:205 / 213
页数:9
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