Steering non-centrosymmetry into the third dimension: crystal engineering of an octupolar nonlinear optical crystal

被引:77
作者
Thalladi, VR
Boese, R
Brasselet, S
Ledoux, I
Zyss, J
Jetti, RKR
Desiraju, GR
机构
[1] Univ Essen Gesamthsch, Inst Anorgan Chem, D-45177 Essen, Germany
[2] Ecole Normale Super Cachan, Dept Phys, F-94235 Cachan, France
[3] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
关键词
D O I
10.1039/a904490f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ability of CH3 groups to form helical chains of C-H ...pi interactions with phenyl rings leads to polar stacking of trigonal octupolar networks in a substituted triazine, and therefore to three-dimensional non-centrosymmetry.
引用
收藏
页码:1639 / 1640
页数:2
相关论文
共 16 条
[1]   Crystal engineering of stacked aromatic columns. Three-dimensional control of the alignment of orthogonal aromatic triads and guest quinones via self-assembly of hydrogen-bonded networks [J].
Aoyama, Y ;
Endo, K ;
Anzai, T ;
Yamaguchi, Y ;
Sawaki, T ;
Kobayashi, K ;
Kanehisa, N ;
Hashimoto, H ;
Kai, Y ;
Masuda, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (24) :5562-5571
[2]  
BRASSELET S, 1996, J NONLINEAR PHYS MAT, V5, P4
[3]   Crystal engineering: solid state supramolecular synthesis [J].
Desiraju, GR .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1997, 2 (04) :451-454
[4]  
DESIRAJU GR, 1986, P INDIAN AS-CHEM SCI, V96, P599
[5]  
DESIRAJU GR, 1999, WEAK HYDROGEN BOND S, P122
[6]   The use of C3-symmetric tripodal ligands in crystal engineering [J].
Hammes, BS ;
Ramos-Maldonado, D ;
Yap, GPA ;
Rheingold, AL ;
Young, VG ;
Borovik, AS .
COORDINATION CHEMISTRY REVIEWS, 1998, 174 :241-253
[7]  
Moylan C. R., 1993, Nonlinear Optics, Principles, Materials, Phenomena and Devices, V6, P113
[8]   Supramolecular structures - Reason and imagination [J].
Nangia, A ;
Desiraju, GR .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1998, 54 :934-944
[9]  
NISHIO M, 1997, CH PI INTERACTION EV, P1953
[10]   STRUCTURAL DEPENDENCE OF NONLINEAR-OPTICAL PROPERTIES OF METHYL-(2,4-DINITROPHENYL)-AMINOPROPANOATE CRYSTALS [J].
OUDAR, JL ;
ZYSS, J .
PHYSICAL REVIEW A, 1982, 26 (04) :2016-2027