Vapor-liquid equilibria for the ternary system ethanol plus water plus 1-butyl-3-methylimidazolium chloride and the corresponding binary systems at 101.3 kPa

被引:97
作者
Calvar, Noelia [1 ]
Gonzalez, Begona [1 ]
Gomez, Elena [1 ]
Dominguez, Angeles [1 ]
机构
[1] Vigo Univ, Dept Chem Engn, Vigo 36310, Spain
关键词
DYNAMIC VISCOSITIES; IONIC LIQUIDS; MIXTURES;
D O I
10.1021/je060293x
中图分类号
O414.1 [热力学];
学科分类号
摘要
this work, experimental data of isobaric vapor-liquid equilibria for the ternary system ethanol + water + 1-butyl-3-methylimidazolium chloride ([C(4)mim][ Cl]) and for the corresponding binary systems containing the ionic liquid ( ethanol + [C(4)mim][Cl] and water + [C(4)mim][Cl]) were measured at 101.3 kPa. Vapor-liquid equilibria experimental data of binary and ternary systems were correlated by the NRTL equation. NRTL parameters have been used to predict the evolution of the ethanol-water azeotrope composition with different amounts of ionic liquid.
引用
收藏
页码:2178 / 2181
页数:4
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