A comparison of microwave and conventional heat treatments of nanocrystalline TiO2

被引:59
作者
Hart, Judy N.
Menzies, David
Cheng, Yi Bing [1 ]
Simon, George P.
Spiccia, Leone
机构
[1] Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia
[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
基金
澳大利亚研究理事会;
关键词
dye-sensitized solar cell; TiO2; microwave processing;
D O I
10.1016/j.solmat.2006.06.059
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
TiO2 thin films are an important component of dye-sensitized solar cells. For these solar cells, the TiO2 film must be sintered to achieve crystallization and good interparticle connections. Microwave processing may allow a reduction in the required temperature and time for this heat treatment. Therefore, microwave heating of nanocrystalline TiO2 has been investigated. No significant difference was found between microwave and conventional heating in the sintering of TiO2, but microwave heating promotes the phase transformation from anatase to rutile. Microwave heating improved the solar cell performance when a surface treatment of the TiO2 film with titanium isopropoxide was applied. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:6 / 16
页数:11
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