Carbon-carbon coupling via nucleophilic addition of a gold(I) methanide complex to heterocumulenes

被引：8

作者：

Bardaji, M

Gimeno, MC

Jones, PG

Laguna, A

Laguna, M

Merchan, F

Romeo, I

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 05期

关键词：

D O I：

10.1021/om960893x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The methanide carbon of [Au(C6F5)(PPh(2)-CHPPh(2)Me)] acts as a nucleophilic center toward reagents such as carbon disulfide and isothiocyanates, affording [Au-III{PPh(2)C(PPh(2)Me)C(X)S}(2)][Au-1(C6F5)(2)] (X = S (I), 4-ClC6H4N (2), PhN (3)) through a carbon-carbon coupling reaction. The X-ray structure of 1 shows the ligand PPh(2)C(PPh(2)Me)C(X)S acting as a bidentate P,S-chelate.

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页码：1083 / 1085

页数：3

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