Supramolecular rotor:: Adamantylammonium([18]crown-6) in [Ni(dmit)2]- salt

被引：44

作者：

Sato, Daisuke

Akutagawa, Tomoyuki

Takeda, Sadamu

Noro, Shin-ichiro

Nakamura, Takayoshi

机构：

[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan

[2] Hokkaido Univ, Grad Sch Environm Earth Sci, Sapporo, Hokkaido 0600810, Japan

[3] Japan Sci & Technol Agcy, CREST, Kawaguchi 3320012, Japan

[4] Hokkaido Univ, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 02期

关键词：

D O I：

10.1021/ic061831u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Adamantylammonium (ADNH(3)(+)) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH(3)(+))([18]crown6), which was introduced into a [Ni(dmit)(2)](-) salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)(2)](-) layers in the crystal, in which the molecular rotation of (ADNH(3)(+))([18]crown-6) was confirmed from the temperature-dependent solid-state H-1 NMR.

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页码：363 / 365

页数：3

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