Adsorption of heavy metal ion from aqueous single metal solution by chemically modified sugarcane bagasse

被引:351
作者
Karnitz, Osvaldo, Jr.
Alves Gurgel, Leandro Vinicius
Perin de Melo, Julio Cesar
Botaro, Vagner Roberto
Sacramento Melo, Tdnia Maircia
de Freitas Gil, Rossimiriam Pereira
Gil, Laurent Frederic [1 ]
机构
[1] Univ Fed Ouro Preto, Dept Quim, Inst Ciencias Exatas & Biol, BR-35400000 Ouro Preto, MG, Brazil
[2] Univ Fed Minas Gerais, Dept Quim, Inst Ciencias Exatas, BR-31270901 Belo Horizonte, MG, Brazil
关键词
adsorption; modified sugarcane bagasse; polyamines; isotherm; heavy metals;
D O I
10.1016/j.biortech.2006.05.013
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
This work describes the preparation of new chelating materials derived from sugarcane bagasse for adsorption of heavy metal ions in aqueous solution. The first part of this report deals with the chemical modification of sugarcane bagasse with succinic anhydride. The carboxylic acid functions introduced into the material were used to anchor polyamines, which resulted in two yet unpublished modified sugarcane bagasse materials. The obtained materials were characterized by elemental analysis and infrared spectroscopy (IR). The second part of this reports features the comparative evaluation of the adsorption capacity of the modified sugarcane bagasse materials for Cu2+. Cd2+, and Pb2+ ions in aqueous single metal solution by classical titration. Adsorption isotherms were studied by the Freundlich and Langmuir models. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1291 / 1297
页数:7
相关论文
共 17 条
[1]   Equilibrium studies on adsorption of Cu(II) from aqueous solution onto cellulose [J].
Acemioglu, B ;
Alma, MH .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 243 (01) :81-84
[2]  
Ali AAH, 1997, J CHEM TECHNOL BIOT, V69, P27, DOI 10.1002/(SICI)1097-4660(199705)69:1<27::AID-JCTB682>3.3.CO
[3]  
2-A
[4]  
[Anonymous], 1996, CIENC TECNOL ALIMENT
[5]  
Baird C, 1995, ENV CHEM
[6]   THERMODYNAMIC ASPECTS OF THE POLYAZACYCLOALKANE COMPLEXES WITH CATIONS AND ANIONS [J].
BIANCHI, A ;
MICHELONI, M ;
PAOLETTI, P .
COORDINATION CHEMISTRY REVIEWS, 1991, 110 (01) :17-113
[7]   Surface properties of lignocellulosic fibers bearing carboxylic groups [J].
Gellerstedt, F ;
Gatenholm, P .
CELLULOSE, 1999, 6 (02) :103-121
[8]   2,3-dihydroxypyridine-loaded cellulose: a new macromolecular chelator for metal enrichment prior to their determination by atomic absorption spectrometry [J].
Gurnani, V ;
Singh, AK ;
Venkataramani, B .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2003, 377 (06) :1079-1086
[9]   Regression analysis for the sorption isotherms of basic dyes on sugarcane dust [J].
Ho, YS ;
Chiu, WT ;
Wang, CC .
BIORESOURCE TECHNOLOGY, 2005, 96 (11) :1285-1291
[10]   A discussion of water pollution in the United States and Mexico; with high school laboratory activities for analysis of lead, atrazine, and nitrate [J].
Kelter, PB ;
Grundman, J ;
Hage, DS ;
Carr, JD ;
CastroAcuna, CM .
JOURNAL OF CHEMICAL EDUCATION, 1997, 74 (12) :1413-1421