Synthesis of ordered mesoporous crystalline carbon-anatase composites with high titania contents

被引：30

作者：

Qian, Xufang ^{[1
]}

Wan, Ying ^{[1
]}

Wen, Yanli ^{[1
]}

Jia, Nengqin ^{[1
]}

Li, Hexing ^{[1
]}

Zhao, Dongyuan ^{[2
]}

机构：

[1] Shanghai Normal Univ, Dept Chem, Shanghai 200234, Peoples R China

[2] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2008年 / 328卷 / 02期

关键词：

Mesoporous; Crystalline; Carbon; Titania; Composite; Hemoglobin; Immobilization; Bioelectrochemical properties;

D O I：

10.1016/j.jcis.2008.08.067

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A direct-triblock-copolymer templating method is demonstrated to synthesize ordered mesoporous crystalline C-TiO2 (MCT) composites using phenolic resins and acid-base pairs [acidic TiCl4 and basic counterpart Ti(OC4H7)(4)] as carbon and titanium sources, respectively. The composites possess highly crystalline anatase pore walls that are "glued" by amorphous carbon, ordered mesostructure, high surface areas (similar to 200 m(2)/g), and large pore volumes (similar to 0.15 cm(3)/g). The titania content is as high as 87 wt%. MCT composite favors the immobilization of proteins and enhances the electrocatalytic properties in relation to the reduction of hydrogen peroxide. (C) 2008 Elsevier Inc. All rights reserved.

引用

页码：367 / 373

页数：7

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