Effective synthesis of cyclic carbonates from carbon dioxide and epoxides by phosphonium iodides as catalysts in alcoholic solvents

被引：90

作者：

Aoyagi, Naoto ^{[1
]}

Furusho, Yoshio ^{[1
]}

Endo, Takeshi ^{[1
]}

机构：

[1] Kinki Univ, Mol Engn Inst, Iizuka, Fukuoka 8208555, Japan

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 51期

关键词：

Phosphonium iodide; Carbon dioxide; 2-Propanol; Cyclic carbonate; Epoxide; CHEMICAL FIXATION; LITHIUM ELECTRODE; IONIC LIQUID; CO2; CAPTURE;

D O I：

10.1016/j.tetlet.2013.10.068

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

Phosphonium iodides effectively catalyzed the reaction of CO2 and epoxides under mild conditions such as ordinary pressure and ambient temperature in 2-propanol, and the corresponding five-membered cyclic carbonates were obtained in high yields. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.

引用

页码：7031 / 7034

页数：4

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