Polysaccharides: The "Click" Chemistry Impact

被引:80
作者
Elchinger, Pierre-Henri [1 ,2 ]
Faugeras, Pierre-Antoine [1 ,2 ]
Boens, Benjamin [1 ]
Brouillette, Francois [2 ]
Montplaisir, Daniel [2 ]
Zerrouki, Rachida [1 ]
Lucas, Romain [3 ]
机构
[1] EA1069, Lab Chim Subst Nat, F-87060 Limoges, France
[2] Univ Quebec Trois Rivieres, Ctr Rech Mat Lignocellulos, Trois Rivieres, PQ G9A 5H7, Canada
[3] CNRS, UMR 6638, Lab Sci Proc Ceram & Traitements Surface, F-87068 Limoges, France
关键词
polysaccharides; click" chemistry; 1; 3-dipolar cycloaddition; azide; alkyne; triazole; catalysis;
D O I
10.3390/polym3041607
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
Polysaccharides are complex but essential compounds utilized in many areas such as biomaterials, drug delivery, cosmetics, food chemistry or renewable energy. Modifications and functionalizations of such polymers are often necessary to achieve molecular structures of interest. In this area, the emergence of the "click" chemistry concept, and particularly the copper-catalyzed version of the Huisgen 1,3-dipolar cycloaddition reaction between terminal acetylenes and azides, had an impact on the polysaccharides chemistry. The present review summarizes the contribution of "click" chemistry in the world of polysaccharides.
引用
收藏
页码:1607 / 1651
页数:45
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