First example of linear strings of equidistant gold atoms in crystals of [(2,4,6-Me3C6H2NC)(2)Au] [Au(GeCl3)(2)]

被引：23

作者：

Bauer, A ^{[1
]}

Schneider, W ^{[1
]}

Schmidbaur, H ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 10期

关键词：

D O I：

10.1021/ic9701468

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Insertion of GeCl2 into the Au-Cl bond of (mesityl isocyanide)gold(I) chloride, followed by a ligand redistribution, leads to the title compound, which crystallizes in strings of alternating cations and anions with linear chains of equidistant gold atoms (Au1-Au2 = 3.435 Angstrom).

引用

页码：2225 / &

页数：3

共 9 条

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[7]

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[8]

Schneider W, 1996, Z NATURFORSCH B, V51, P790

[9]

SHELDRICK G, 1993, SHELXL 93

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