The effect of poly(ethylene terephthalate) and polyethylene as admixtures in, on dehydrochlorination of, poly(vinyl chloride)

被引：3

作者：

German, K ^{[1
]}

Kulesza, K ^{[1
]}

机构：

[1] Krakow Tech Univ, Dept Chem & Technol Polymers, PL-31155 Krakow, Poland

来源：

POLIMERY | 1999年 / 44卷 / 7-8期

关键词：

poly(vinyl chloride); recycling of PVC; mechanism of dehydrochlorination of PVC;

D O I：

10.14314/polimery.1999.548

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dehydrochlorination (DHC) of PVC was studied in the presence of PET and PE as admixtures by using conductometry to determine the forming HCl. The admixtures were found to suppress the maximum degree of DHC and to reduce the rate of DHC. The kinetic data showed the Diels-Alder mechanism to be involved in the zip termination reaction. CC-MS data showed PET as admixture to result in no organochlorine compounds present in the pyrolyzates of (PVC + PET) mixtures.

引用

页码：548 / 551

页数：4

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