Size-selective incorporation of CdS nanoparticles into mesoporous silica

被引：138

作者：

Hirai, T ^{[1
]}

Okubo, H

Komasawa, I

机构：

[1] Osaka Univ, Dept Sci & Chem Engn, Grad Sch Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Osaka Univ, Res Ctr Photoenerget Organ Mat, Toyonaka, Osaka 5608531, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1999年 / 103卷 / 21期

关键词：

D O I：

10.1021/jp990496a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

CdS nanoparticles, prepared in reverse micellar systems, were incorporated into thiol-modified MCM-41 (FM41) mesoporous material, of differing pore sizes, designated as large (L-FM41), middle (M-FM41), and small (S-FM41). A particle-sieving effect of the FM41 was observed, in that the incorporation of the CdS nanoparticles was decreased by increased size of particle, and by a decreasing pore size of the FM41. The resulting CdS-FM41 composite showed photocatalytic activity for H-2 generation from water.

引用

页码：4228 / 4230

页数：3

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