A facile one-pot route to transparent polymer nanocomposites with high ZnS nanophase contents via in situ bulk polymerization

被引：42

作者：

Guan, Cheng ^{[1
]}

Lue, Changli ^{[2
]}

Cheng, Yuanrong ^{[1
]}

Song, Shouyin ^{[1
]}

Yang, Bai ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Supramol Struct & Mat, Coll Chem, Changchun 130012, Peoples R China

[2] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2009年 / 19卷 / 05期

基金：

中国国家自然科学基金;

关键词：

MECHANICAL-PROPERTIES; GAS/SOLID REACTION; THIN-FILMS; COMPOSITE; SURFACE; NANOCRYSTALLITES; NANOPARTICLES; HYBRID; IRRADIATION;

D O I：

10.1039/b818876a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transparent polymer nanocomposites with high ZnS nanophase contents were prepared by a facile one-pot route. Compared with other methods, this method is easier to control. The structure, morphology, thermal and optical properties of the obtained nanocomposites were characterized. The results showed that the ZnS nanoparticles with an average size of 3 nm were dispersed uniformly in the polymer matrix. The ZnS nanoparticles and the polymer matrix were linked by covalent-bonds, which improved the nanocomposite's thermal behavior and mechanical properties. Due to the controlled structure and ZnS content, the nanocomposites had good transparency and the refractive index was continuously adjustable.

引用

页码：617 / 621

页数：5

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