Different synthetic routes towards efficient organogelators: 2,3-substituted anthracenes

被引:59
作者
Pozzo, JL
Clavier, GM
Colomes, M
BouasLaurent, H
机构
[1] Laboratoire de Photochimie Organique, URA CNRS 348, Université Bordeaux I
关键词
D O I
10.1016/S0040-4020(97)00297-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Three synthetic approaches towards 2,3-substituted anthracenes are reported and discussed in terms of selectivity and viability. This allowed us to introduce a variety of substituents as sidearms. Promising results have been found using a tandem Diels-Alder aromatization reaction using 2,3-dimethoxybutadiene 9 as a key intermediate. However, for multigram preparations the Friedel-Crafts approach is preferred. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:6377 / 6390
页数:14
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