Hierarchically Micro- and Mesoporous Metal-Organic Frameworks with Tunable Porosity

被引:372
作者
Qiu, Ling-Guang [1 ]
Xu, Tao [1 ]
Li, Zong-Qun [1 ]
Wang, Wei [1 ]
Wu, Yun [1 ]
Jiang, Xia [1 ]
Tian, Xing-You [2 ]
Zhang, Li-De [2 ]
机构
[1] Anhui Univ, Sch Chem & Chem Engn, Hefei 230039, Peoples R China
[2] Chinese Acad Sci, Inst Solid State Phys, Hefei 230031, Peoples R China
基金
中国国家自然科学基金;
关键词
mesoporous materials; metal-organic frameworks; microporous materials; organic-inorganic hybrid composites; zeolite analogues;
D O I
10.1002/anie.200803640
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) A new hierarchy: A supramolecular template strategy is used to synthesize hierarchical micro- and mesoporous metal-organic frameworks. The mesopore walls are constructed from a microporous framework (see picture). The porosity can be tuned by using different templates at various molar ratios. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:9487 / 9491
页数:5
相关论文
共 46 条
[1]  
[Anonymous], 2004, Angew. Chem, V116, P2388, DOI DOI 10.1016/j.jechem.2020.01.001
[2]   Porous material for absorption and luminescent detection of aromatic molecules in water [J].
Bai, Y ;
He, GJ ;
Zhao, YG ;
Duan, CY ;
Dang, DB ;
Meng, QJ .
CHEMICAL COMMUNICATIONS, 2006, (14) :1530-1532
[3]  
Batten S.R., 1998, ANGEW CHEM, V110, P1558, DOI DOI 10.1002/(SICI)1521-3757(19980605)110:11<1558::AID-ANGE1558>3.0.CO
[4]  
2-7
[5]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[6]  
2-Z
[7]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[8]   A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].
Chui, SSY ;
Lo, SMF ;
Charmant, JPH ;
Orpen, AG ;
Williams, ID .
SCIENCE, 1999, 283 (5405) :1148-1150
[9]   Ordered porous materials for emerging applications [J].
Davis, ME .
NATURE, 2002, 417 (6891) :813-821
[10]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472