Developments in CO2 research

被引:35
作者
Behles, JA [1 ]
DeSimone, JM [1 ]
机构
[1] Univ N Carolina, Dept Chem, Venable & Kenan Labs, Chapel Hill, NC 27599 USA
关键词
D O I
10.1351/pac200173081281
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CO2 can be a good solvent for many compounds when used in its compressed liquid or supercritical fluid state. Above its critical temperature and critical pressure (T-C = 31 degreesC. P-c = 73.8 bar), CO2 has liquid-like densities and gas-like viscosities, which allows for safe commercial and laboratory operating conditions. Many small molecules are readily soluble in CO2, whereas most macromolecules are not. This has prompted development of several classes of small molecule and polymeric surfactants that enable emulsion and dispersion polymerizations as well as other technological processes.
引用
收藏
页码:1281 / 1285
页数:5
相关论文
共 30 条
[1]  
BARER S, 1988, CATALYTIC ACTIVATION
[2]  
BETTS D, 1996, HIGH PRESSURE CHEM E
[3]  
BETTS D, 1997, POLYM PREPR AM CHEM, V38, P760
[4]   Dispersion polymerization of styrene in supercritical carbon dioxide: Importance of effective surfactants [J].
Canelas, DA ;
Betts, DE ;
DeSimone, JM .
MACROMOLECULES, 1996, 29 (08) :2818-2821
[5]   Poly(vinyl acetate) and poly(vinyl acetate-co-ethylene) latexes via dispersion polymerizations in carbon dioxide [J].
Canelas, DA ;
Betts, DE ;
DeSimone, JM ;
Yates, MZ ;
Johnston, KP .
MACROMOLECULES, 1998, 31 (20) :6794-6805
[6]   Dispersion polymerizations of styrene in carbon dioxide stabilized with poly(styrene-b-dimethylsiloxane) [J].
Canelas, DA ;
DeSimone, JM .
MACROMOLECULES, 1997, 30 (19) :5673-5682
[7]   Dispersion polymerization of 1-vinyl-2-pyrrolidone in supercritical carbon dioxide [J].
Carson, T ;
Lizotte, J ;
Desimone, JM .
MACROMOLECULES, 2000, 33 (06) :1917-1920
[8]   HOMOGENEOUS FREE-RADICAL POLYMERIZATIONS IN CARBON-DIOXIDE .3. TELOMERIZATION OF 1,1-DIFLUOROETHYLENE IN SUPERCRITICAL CARBON-DIOXIDE [J].
COMBES, JR ;
GUAN, Z ;
DESIMONE, JM .
MACROMOLECULES, 1994, 27 (03) :865-867
[9]   DISPERSION POLYMERIZATIONS IN SUPERCRITICAL CARBON-DIOXIDE [J].
DESIMONE, JM ;
MAURY, EE ;
MENCELOGLU, YZ ;
MCCLAIN, JB ;
ROMACK, TJ ;
COMBES, JR .
SCIENCE, 1994, 265 (5170) :356-359
[10]   AGGREGATION OF AMPHIPHILIC MOLECULES IN SUPERCRITICAL CARBON-DIOXIDE - A SMALL-ANGLE X-RAY-SCATTERING STUDY [J].
FULTON, JL ;
PFUND, DM ;
MCCLAIN, JB ;
ROMACK, TJ ;
MAURY, EE ;
COMBES, JR ;
SAMULSKI, ET ;
DESIMONE, JM ;
CAPEL, M .
LANGMUIR, 1995, 11 (11) :4241-4249