A study on the selective phosphorylation and phosphinylation of hydroxyphenols

被引：9

作者：

Marosi, G

Toldy, A

Parlagh, G

Nagy, Z

Ludányi, K

Anna, P

Keglevich, G ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1521 Budapest, Hungary

[2] Budapest Univ Technol & Econ, Dept Phys Chem, H-1521 Budapest, Hungary

[3] Gedeon Richter Chem Works Ltd, H-1475 Budapest, Hungary

[4] Hungarian Acad Sci, Chem Res Ctr, H-1525 Budapest, Hungary

来源：

HETEROATOM CHEMISTRY | 2002年 / 13卷 / 02期

关键词：

D O I：

10.1002/hc.10006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By choice of appropriate reaction conditions, the phosphorylation of hydroquinone by diethyl chlorophosphate gave predominantly the monophosphate (2). A similar reaction of phloroglucinol led to the mixture of the possible products (6, 7, and 8). The monophosphinylation of the above hydroxyphenols by diphenylphosphinyl chloride could be accomplished with a good selectivity to give product 4 or 9, the yields, however, being variable. (C) 2002 Wiley Periodicals, Inc.

引用

页码：126 / 130

页数：5

共 16 条

[1]

EDMUNDSON RS, 1991, CRC HDB PHOSPHORUS, V31, P360

[2] METAL PHOSPHINYLIDES AND PHOSPHINOTHIOYLIDES .2. EFFECTS OF METALS ON REACTIONS OF [PH2PX]M WITH BENZALDEHYDE AND PARA-BENZOQUINONE [J].