Polymeric bicontinuous microemulsions

被引：302

作者：

Bates, FS

Maurer, WW

Lipic, PM

Hillmyer, MA

Almdal, K

Mortensen, K

Fredrickson, GH

Lodge, TP

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

[2] RISO NATL LAB,DK-4000 ROSKILDE,DENMARK

[3] UNIV CALIF SANTA BARBARA,DEPT CHEM ENGN,SANTA BARBARA,CA 93106

来源：

PHYSICAL REVIEW LETTERS | 1997年 / 79卷 / 05期

关键词：

D O I：

10.1103/PhysRevLett.79.849

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

High molecular weight block copolymers can be viewed as macromolecular surfactants when blended with thermodynamically incompatible homopolymers. This Letter describes the formation of polymeric bicontinuous microemulsions in nurtures containing a model diblock copolymer and two homopolymers. Although we attribute development of this equilibrium morphology to the effects of fluctuations, mean-field theory provides a quantitative strategy for preparing the bicontinuous state at blend compositions near an isotropic Lifshitz point.

引用

页码：849 / 852

页数：4

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