Dehydrogenation of ethylbenzene to styrene in the presence of CO2 over calcined hydrotalcite-like compounds as catalysts

被引:41
作者
Mimura, N
Takahara, I
Saito, M
Sasaki, Y
Murata, K
机构
[1] Natl Inst Adv Ind Sci & Technol, Res Inst Green Technol, Hydrocarbon Convers Catalyst Grp, Tsukuba W, Tsukuba, Ibaraki 3058569, Japan
[2] Natl Inst Adv Ind Sci & Technol, Hydrocarbon Convers Grp, AIST Tsukuba Cent 5, Tsukuba, Ibaraki 3058566, Japan
关键词
ethylbenzene; styrene; dehydrogenation; hydrotalcite; CO2;
D O I
10.1023/A:1014902111562
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Calcined hydrotalcite-like compounds were effective catalysts for the dehydrogenation of ethylbenzene in the presence of CO2 as an oxidant. X-ray diffraction patterns suggested that the catalyst components are distributed uniformly. The activity (area] rate) of Fe(l)/Al(2)/Zn(6) oxide catalyst (molar ratios in parentheses) was the highest among the catalysts tested.
引用
收藏
页码:125 / 128
页数:4
相关论文
共 12 条
[1]   Screening of catalysts in the oxidative dehydrogenation of ethylbenzene with carbon dioxide [J].
Badstube, T ;
Papp, H ;
Dziembaj, R ;
Kustrowski, P .
APPLIED CATALYSIS A-GENERAL, 2000, 204 (01) :153-165
[2]   Oxidative dehydrogenation of ethylbenzene with carbon dioxide on alkali-promoted Fe active carbon catalysts [J].
Badstube, T ;
Papp, H ;
Kustrowski, P ;
Dziembaj, R .
CATALYSIS LETTERS, 1998, 55 (3-4) :169-172
[3]   Beneficial effect of carbon dioxide in dehydrogenation of ethylbenzene to styrene over zeolite-supported iron oxide catalyst [J].
Chang, JS ;
Park, SE ;
Park, MS .
CHEMISTRY LETTERS, 1997, (11) :1123-1124
[4]   SYNTHESIS AND PROPERTIES OF ANIONIC CLAYS PILLARED BY [XM12O40]N- KEGGIN IONS [J].
KWON, T ;
PINNAVAIA, TJ .
JOURNAL OF MOLECULAR CATALYSIS, 1992, 74 (1-3) :23-33
[5]   ANION-EXCHANGE REACTIONS OF LAYERED DOUBLE HYDROXIDES [J].
MEYN, M ;
BENEKE, K ;
LAGALY, G .
INORGANIC CHEMISTRY, 1990, 29 (26) :5201-5207
[6]   Dehydrogenation of ethylbenzene to styrene over Fe2O3/Al2O3 catalysts in the presence of carbon dioxide [J].
Mimura, N ;
Saito, M .
CATALYSIS TODAY, 2000, 55 (1-2) :173-178
[7]   Dehydrogenation of ethylbenzene to styrene over Fe2O3/Al2O3 catalysts in the presence of carbon dioxide [J].
Mimura, N ;
Saito, M .
CATALYSIS LETTERS, 1999, 58 (01) :59-62
[8]   Dehydrogenation of ethylbenzene over iron oxide-based catalyst in the presence of carbon dioxide [J].
Mimura, N ;
Takahara, I ;
Saito, M ;
Hattori, T ;
Ohkuma, K ;
Ando, M .
CATALYSIS TODAY, 1998, 45 (1-4) :61-64
[9]   Dehydrogenation of ethylbenzene with an activated carbon-supported vanadium catalyst [J].
Sakurai, Y ;
Suzaki, T ;
Ikenaga, N ;
Suzuki, T .
APPLIED CATALYSIS A-GENERAL, 2000, 192 (02) :281-288
[10]   Oxidation capability of carbon dioxide in the dehydrogenation of ethylbenzene over vanadium oxide-loaded MgO catalyst [J].
Sakurai, Y ;
Suzaki, T ;
Nakagawa, K ;
Ikenaga, N ;
Aota, H ;
Suzuki, T .
CHEMISTRY LETTERS, 2000, (05) :526-527