Hexakis(acetonitrile)iron(II) hexafluoroantimonate

被引：9

作者：

Brennessel, WW ^{[1
]}

Brooks, NR ^{[1
]}

Mehn, MP ^{[1
]}

Que, L ^{[1
]}

Young, VG ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801017585

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Fe(C2H3N)(6)][SbF6](2), (I), synthesized by reaction of AgSbF6 with FeCl2 in CH3CN, is isostructural with the analogous nickel complex [see Leban et al. (1987), Acta Cryst. C43, 1888-1890]. The Fe II centre in the cation occupies a crystallographic (3) over bar site and is octahedrally coordinated by six acetonitrile ligands, with an Fe-N distance of 2.153 (2) Angstrom and an N-Fe-N angle of 88.05 (10)degrees. The SbF6- anion lies on a crystallographic threefold rotation axis. [GRAPHICS]

引用

页码：M545 / M546

页数：2

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