Thermodynamic modeling of the solubility of salts in mixed aqueous-organic solvents

被引：28

作者：

Kolker, A ^{[1
]}

dePablo, J ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM ENGN,MADISON,WI 53706

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1996年 / 35卷 / 01期

关键词：

D O I：

10.1021/ie9406207

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A semiempirical thermodynamic model is proposed for prediction of the solubility of salts in mixed aqueous-organic solvents. This model requires only standard thermodynamic properties for the pure components and for the solutes at infinite dilution in each solvent. The new method is illustrated with predictions of solubility for several salts in mixtures of water with methanol and ethanol. The method developed here could be of particular interest for process calculations and design of low-energy extractive crystallization methods for production of salts from aqueous solutions.

引用

页码：228 / 233

页数：6

共 21 条

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CHEN CC, 1980, ACS S SERIES, V133

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