Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

被引：415

作者：

Cheung, P

Bhan, A

Sunley, GJ

Iglesia, E ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA

[2] BP Chem Ltd, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 10期

关键词：

carbonylation; carboxylic acids; ethers; heterogeneous catalysis; zeolites;

D O I：

10.1002/anie.200503898

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

(Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1617 / 1620

页数：4

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