Synthesis and spectral investigation of alkyl methacrylates with halogenated carbazolyl pendant groups for photonics applications

被引:10
作者
Bogdal, D
Yashchuk, V
Pielichowski, J
Ogul'Chansky, T
Warzala, M
Kudrya, V
机构
[1] Krakow Tech Univ, Katedra Chem & Technol Tworzyw Sztucznych, PL-31155 Krakow, Poland
[2] Kyiv Natl Taras Shevchenko Univ, Dept Phys, UA-03127 Kiev, Ukraine
关键词
functionalization of polymers; luminescence; fluorescence; phosphorescence;
D O I
10.1002/app.10469
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The alkyl methacrylates with halogenated carbazolyl pendant groups were prepared, and the analysis of their absorption and emission spectra showed that the polymers containing monohalogenatged carbazole rings were capable of exhibiting a high singlet-triplet (S-T) conversion. The reasons that mainly triplet excitons could be observed in such polymers and additional bands appearance in the spectra of the polymers with dihalogenated carbazole rings are discussed. (C) 2002 Wiley Periodicals, Inc.
引用
收藏
页码:1650 / 1656
页数:7
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