Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries

被引：390

作者：

Doe, Robert E. ^{[1
]}

Han, Ruoban ^{[1
]}

Hwang, Jaehee ^{[1
]}

Gmitter, Andrew J. ^{[1
]}

Shterenberg, Ivgeni ^{[2
]}

Yoo, Hyun Deog ^{[2
]}

Pour, Nir ^{[2
]}

Aurbach, Doron ^{[2
]}

机构：

[1] Pell Technol, Cambridge, MA 02139 USA

[2] Bar Ilan Univ, Dept Chem, IL-92100 Ramat Gan, Israel

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 02期

关键词：

STRUCTURAL-ANALYSIS; COMPLEXES;

D O I：

10.1039/c3cc47896c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid-base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.

引用

页码：243 / 245

页数：3