Divergent synthesis of carbosilane wedges as dendritic building blocks: a new strategy towards core functionalised carbosilane dendrimers

被引:25
作者
van Heerbeek, R [1 ]
Reek, JNH [1 ]
Kamer, PCJ [1 ]
van Leeuwen, PWNM [1 ]
机构
[1] Univ Amsterdam, Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands
关键词
dendrimers; molecular recognition; complexation; amino acids;
D O I
10.1016/S0040-4039(99)01476-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A divergent route for the synthesis of carbosilane wedges containing either a bromine or amine as a focal point has been developed for the construction of core functionalised dendrimers; carbosilane dendrimers up to the third generation containing a 1,3,5-benzene triamide core capable of binding guest molecules via hydrogen bonding have been prepared. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:7127 / 7130
页数:4
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