Surface core-level shift photoelectron diffraction study of β-SiC(001)-c(2 x 2) surface

被引:9
作者
Shimomura, M [1 ]
Yeom, HW
Mun, BS
Fadley, CS
Hara, S
Yoshida, S
Kono, S
机构
[1] Tohoku Univ, Sci Measurements Res Inst, Sendai, Miyagi 9808577, Japan
[2] Univ Tokyo, Res Ctr Spectrochem, Tokyo 1130033, Japan
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
[4] Electrotech Lab, Tsukuba, Ibaraki 3058568, Japan
关键词
photoelectron diffraction; silicon carbide; surface relaxation and reconstruction;
D O I
10.1016/S0039-6028(99)00575-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Surface core-level shift energy scan photoelectron diffraction (PED) was used to distinguish the two structural models of the C-terminated beta-SiC(001)-c(2 x 2) surface under debate. An experimental FED curve of the surface C Is component is in good agreement only with the simulated curve of the unusual bridge dimer model denying the conventional dimer model. The optimized structural parameters of this bridge dimer model are 1.22, 1.84 and 2.7 Angstrom for the C-C, C-Si and Si-Si bond lengths, respectively, in agreement with recent theoretical calculations. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:237 / 241
页数:5
相关论文
共 14 条
[1]   ENERGETICS OF THE C(2X2) RECONSTRUCTION OF THE BETA-SIC(100) SURFACE [J].
BADZIAG, P .
PHYSICAL REVIEW B, 1991, 44 (20) :11143-11148
[2]   PREPARATION AND CHARACTERIZATION OF CARBON-TERMINATED BETA-SIC(001) SURFACES [J].
BERMUDEZ, VM ;
KAPLAN, R .
PHYSICAL REVIEW B, 1991, 44 (20) :11149-11158
[3]   Reconstruction and thermal stability of the cubic SiC(001) surfaces [J].
Catellani, A ;
Galli, G ;
Gygi, F .
PHYSICAL REVIEW LETTERS, 1996, 77 (25) :5090-5093
[4]   Convergence and reliability of the Rehr-Albers formalism in multiple-scattering calculations of photoelectron diffraction [J].
Chen, Y ;
de Abajo, FJG ;
Chasse, A ;
Ynzunza, RX ;
Kaduwela, AP ;
Van Hove, MA ;
Fadley, CS .
PHYSICAL REVIEW B, 1998, 58 (19) :13121-13131
[5]  
CRAIG BI, 1991, SURF SCI, V256, pL609, DOI 10.1016/0039-6028(91)91193-2
[6]  
HOFFMAN P, 1994, SURF SCI, V304, P74
[7]   High resolution soft x-ray bending magnet beamline 9.3.2 with circularly polarized radiation capability at the advanced light source [J].
Hussain, Z ;
Huff, WRA ;
Kellar, SA ;
Moler, EJ ;
Heimann, PA ;
McKinney, W ;
Padmore, HA ;
Fadley, CS ;
Shirley, DA .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1996, 80 :401-404
[8]   SURFACE-STRUCTURE AND COMPOSITION OF BETA-SIC AND 6H-SIC [J].
KAPLAN, R .
SURFACE SCIENCE, 1989, 215 (1-2) :111-134
[9]   Structural determination of beta-SiC(100)-c(2x2) from C-1s surface-core-exciton and Si-2p absorption [J].
Long, JP ;
Bermudez, VM ;
Ramaker, DE .
PHYSICAL REVIEW LETTERS, 1996, 76 (06) :991-994
[10]   STRUCTURAL-ANALYSIS OF THE BETA-SIC(100)-C(2X2) SURFACE RECONSTRUCTION BY AUTOMATED TENSOR LOW-ENERGY ELECTRON-DIFFRACTION [J].
POWERS, JM ;
WANDER, A ;
ROUS, PJ ;
VANHOVE, MA ;
SOMORJAI, GA .
PHYSICAL REVIEW B, 1991, 44 (20) :11159-11166