Electrosorption of neutral organic compounds from solvents of high dielectric constant. Triphenylphosphine oxide as a probe molecule

被引：14

作者：

Anastopoulos, AG

机构：

[1] Laboratory of Physical Chemistry, Department of Chemistry, Aristotle University of Thessaloniki

来源：

ELECTROCHIMICA ACTA | 1996年 / 41卷 / 16期

关键词：

non-ionic; adsorption; pure; non-aqueous; solvents;

D O I：

10.1016/0013-4686(96)00067-9

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The adsorption of triphenylphosphine oxide at the mercury electrode. From solvents of high dielectric constant, is studied by means of capacitance measurements against potential and time. The usual interfacial parameters are determined and discussed. The calculated values of the Gibbs energy of maximum adsorption are found to be in satisfactory correlation with donor properties of the solvets used. Copyright (C) 1996 Elsevier Science Ltd.

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页码：2537 / 2544

页数：8

相关论文

共 19 条

[1] ADSORPTION OF ALIPHATIC NITRILES AT MERCURY-AQUEOUS SOLUTION INTERFACE [J].

ABDELNABEY, BA ;

DEBATTISTI, A ;

TRASATTI, S .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1977, 60 (01) :67-71

[2]

Damaskin B. B., 1971, ADSORPTION ORGANIC C

[3] THE ADSORPTION OF BROMIDE IONS ON MERCURY FROM PROPYLENE CARBONATE SOLUTIONS OF CONSTANT IONIC-STRENGTH [J].

FAWCETT, WR ;

MOTHEO, AJ .

ELECTROCHIMICA ACTA, 1991, 36 (13) :1971-1977

[4] COMPARISON OF SOLVENT EFFECTS IN THE KINETICS OF SIMPLE ELECTRON-TRANSFER AND AMALGAM FORMATION REACTIONS [J].

FAWCETT, WR .

LANGMUIR, 1989, 5 (03) :661-671

[5] THE INFLUENCE OF ALKANES AND BENZENE-DERIVATIVES ON THE DOUBLE-LAYER PROPERTIES OF MERCURY NONAQUEOUS CH3CN ELECTROLYTES [J].

GAMBERT, R ;

BAUMGARTEL, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 185 (01) :147-161

[6] SOLVENT EFFECTS ON HALF-WAVE POTENTIALS [J].

GRITZNER, G .

JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (21) :5478-5485

[7]

GUPTA SL, 1972, Z NATURFORSCH PT B, VB 27, P634

[8]

JAPARIDZE J, 1986, ELECTROCHIM ACTA, V11, P621

[9] ADSORPTION OF ORGANIC-SUBSTANCES AT THE MERCURY ETHYLENE-GLYCOL INTERFACE .2. AROMATIC-COMPOUNDS [J].

JAPARIDZE, JI ;

JAPARIDZE, SS ;

ABULADZE, NA ;

DEBATTISTI, A ;

TRASATTI, S .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :2481-2495

[10] COMPLEMENTARY LEWIS ACID-BASE DESCRIPTION OF SOLVENT EFFECTS .1. ION-ION AND ION-DIPOLE INTERACTIONS [J].

KRYGOWSKI, TM ;

FAWCETT, WR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (08) :2143-2148