Remarkable homology in the electronic spectra of the mixed-valence cation and anion radicals of a conjugated bis(porphyrinyl)butadiyne

被引：35

作者：

Arnold, DP ^{[1
]}

Hartnell, RD

Heath, GA

Newby, L

Webster, RD

机构：

[1] Queensland Univ Technol, Sch Phys & Chem Sci, Brisbane, Qld 4001, Australia

[2] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b200803n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pi-radical cation and anion of the dizinc complex of a bis(triarylporphyrinyl) butadiyne, 1(+) and 1(-), respectively, display remarkably similar near- IR signatures, with intense bands near 1000 and 2500 nm, as predicted by the appropriate frontier- orbital model for inter- porphyrin coupling across the conjugated bridge.

引用

页码：754 / 755

页数：2

共 33 条

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