Preparation of chiral triarylphosphines by Pd-catalysed asymmetric P-C cross-coupling

被引：96

作者：

Korff, C ^{[1
]}

Helmchen, G ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 05期

关键词：

D O I：

10.1039/b315009g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantioselective C-P cross-coupling of diarylphosphines and ortho-substituted aryl iodides has been achieved with >90%ee, using an in situ catalyst prepared from Et,Et-FerroTANE, Pd-2(dba)(3)xCHCl(3) and LiBr.

引用

页码：530 / 531

页数：2

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