Ring-opening copolymerization of (R)-β-butyrolactone with macrolide:: A new series of poly(hydroxyalkanoate)s

被引：24

作者：

Hori, Y ^{[1
]}

Hongo, H ^{[1
]}

Hagiwara, T ^{[1
]}

机构：

[1] Takasago Int Corp, Cent Res Lab, Hiratsuka, Kanagawa 2540073, Japan

来源：

MACROMOLECULES | 1999年 / 32卷 / 10期

关键词：

D O I：

10.1021/ma981846e

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The ring-opening copolymerization of (R)-β-butyrolactone (R)-BL) with several lactones was attempted using distannoxane complexes as new catalysts. A new series of poly(hydroxyalkanoate)s comprised of (R)-3-hydroxybutanoate was obtained. The elongation-to-breaks of P[(R)-3HB-co-10% 15-PD] and P[(R)-3HB-co-10% 16-HD] were unexpectedly and extremely large.

引用

页码：3537 / 3539

页数：3

共 12 条

[1]

Brandl H, 1990, Adv Biochem Eng Biotechnol, V41, P77

[2]

Dawes E.A., 1990, Novel biodegradable microbial polymers, V1st

[3]

Doi Y., 1990, MICROBIAL POLYESTERS

[4]

Holmes P.A., 1988, DEV CRYSTALLINE POLY, V2, P1, DOI DOI 10.1007/978-94-009-1341-71.

[5] RING-OPENING POLYMERIZATION OF OPTICALLY-ACTIVE BETA-BUTYROLACTONE USING DISTANNOXANE CATALYSTS - SYNTHESIS OF HIGH-MOLECULAR-WEIGHT POLY(3-HYDROXYBUTYRATE) [J].

HORI, Y ;

SUZUKI, M ;

YAMAGUCHI, A ;

NISHISHITA, T .

MACROMOLECULES, 1993, 26 (20) :5533-5534

[6] CHEMICAL SYNTHESIS OF HIGH-MOLECULAR-WEIGHT POLY(3-HYDROXYBUTYRATE-CO-4-HYDROXYBUTYRATE) [J].

HORI, Y ;

YAMAGUCHI, A ;

HAGIWARA, T .

POLYMER, 1995, 36 (24) :4703-4705

[7] Ring-opening copolymerization of (R)-beta-butyrolactone with cyclic carbonates: New biodegradable poly(ester carbonate)s [J].

Hori, Y ;

Gonda, Y ;

Takahashi, Y ;

Hagiwara, T .

MACROMOLECULES, 1996, 29 (02) :804-806

[8] RING-OPENING COPOLYMERIZATION OF OPTICALLY-ACTIVE BETA-BUTYROLACTONE WITH SEVERAL LACTONES CATALYZED BY DISTANNOXANE COMPLEXES - SYNTHESIS OF NEW BIODEGRADABLE POLYESTERS [J].

HORI, Y ;

TAKAHASHI, Y ;

YAMAGUCHI, A ;

NISHISHITA, T .

MACROMOLECULES, 1993, 26 (16) :4388-4390

[9] RING-OPENING COPOLYMERIZATION OF (R)-BETA-BUTYROLACTONE WITH (R)-3-METHYL-4-OXA-6-HEXANOLIDE - A NEW BIODEGRADABLE POLY(ESTER-ETHER) [J].

HORI, Y ;

YAMAGUCHI, A .

MACROMOLECULES, 1995, 28 (01) :406-408

[10] CHEMICAL SYNTHESIS OF NOVEL BIODEGRADABLE POLYESTERS [J].

HORI, Y ;

TAKAHASHI, Y ;

YAMAGUCHI, A ;

HAGIWARA, T .

CANADIAN JOURNAL OF MICROBIOLOGY, 1995, 41 :282-288

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