Remarkable stereocontrol in the polymerization of racemic lactide using aluminum initiators supported by tetradentate aminophenoxide ligands

被引：495

作者：

Hormnirun, P ^{[1
]}

Marshall, EL ^{[1
]}

Gibson, VC ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, London SW7 2AY, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 09期

关键词：

D O I：

10.1021/ja038757o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new family of aluminum complexes bearing tetradentate bis(aminophenoxide) ligands is reported and shown to initiate the living ring-opening polymerization of rac-lactide. The microstructures of the polylactide products are found to be highly dependent upon the ancillary ligand substituents, ranging from highly isotactic (Pm = 0.79) to very highly heterotactic (Pr = 0.96). Copyright © 2004 American Chemical Society.

引用

页码：2688 / 2689

页数：2

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