Characterization of treated indium-tin-oxide surfaces used in electroluminescent devices

被引:337
作者
Mason, MG [1 ]
Hung, LS
Tang, CW
Lee, ST
Wong, KW
Wang, M
机构
[1] Eastman Kodak Co, Imaging Res & Adv Dev, Rochester, NY 14650 USA
[2] City Univ Hong Kong, Dept Phys & Mat Sci, Hong Kong, Peoples R China
关键词
D O I
10.1063/1.370948
中图分类号
O59 [应用物理学];
学科分类号
摘要
The influence of oxidative and reductive treatments of indium-tin-oxide (ITO) on the performance of electroluminescent devices is presented. The improvement in device performance is correlated with the surface chemical composition and work function. The work function is shown to be largely determined by the surface oxygen concentration. Oxygen-glow discharge or ultraviolet-ozone treatments increase the surface oxygen concentration and work function in a strongly correlated manner. High temperature, vacuum annealing reduces both the surface oxygen and work function. With oxidation the occupied, density of states (DOS) at the Fermi level is also greatly reduced. This process is reversible by vacuum annealing and it appears that the oxygen concentration, work function, and DOS can be cycled by repeated oxygen treatments and annealing. These observations are interpreted in terms of the well-known, bulk properties of ITO. (C) 1999 American Institute of Physics. [S0021-8979(99)07815-9].
引用
收藏
页码:1688 / 1692
页数:5
相关论文
共 22 条
[1]   Polymeric anodes for improved polymer light-emitting diode performance [J].
Carter, SA ;
Angelopoulos, M ;
Karg, S ;
Brock, PJ ;
Scott, JC .
APPLIED PHYSICS LETTERS, 1997, 70 (16) :2067-2069
[2]   ELECTRON INJECTION IN THIN FILMS OF COPPER PHTALOCYANINE [J].
DELACOTE, GM ;
FILLARD, JP ;
MARCO, FJ .
SOLID STATE COMMUNICATIONS, 1964, 2 (12) :373-376
[3]  
EASTMAN DE, 1981, PHYS REV B, V24, P3647, DOI 10.1103/PhysRevB.24.3647
[4]  
Fadley C., 1978, ELECT SPECTROSCOPY T, VII
[5]  
FORSYTHE E, 1998, COMMUNICATION
[6]   An organic electroluminescent dot-matrix display using carbon underlayer [J].
Gyoutoku, A ;
Hara, S ;
Komatsu, T ;
Shirinashihama, M ;
Iwanaga, H ;
Sakanoue, K .
SYNTHETIC METALS, 1997, 91 (1-3) :73-75
[7]  
HAMBERG I, 1986, J APPL PHYS, V60, P123
[8]   CARRIER INJECTION INTO SEMICONDUCTING POLYMERS - FOWLER-NORDHEIM FIELD-EMISSION TUNNELING [J].
HEEGER, AJ ;
PARKER, ID ;
YANG, Y .
SYNTHETIC METALS, 1994, 67 (1-3) :23-29
[9]   Enhanced electron injection in organic electroluminescence devices using an Al/LiF electrode [J].
Hung, LS ;
Tang, CW ;
Mason, MG .
APPLIED PHYSICS LETTERS, 1997, 70 (02) :152-154
[10]   Indium-tin oxide treatments for single- and double-layer polymeric light-emitting diodes: The relation between the anode physical, chemical, and morphological properties and the device performance [J].
Kim, JS ;
Granstrom, M ;
Friend, RH ;
Johansson, N ;
Salaneck, WR ;
Daik, R ;
Feast, WJ ;
Cacialli, F .
JOURNAL OF APPLIED PHYSICS, 1998, 84 (12) :6859-6870