Flavin-based [2]rotaxanes

被引:19
作者
Cooke, Graeme
Garety, James F.
Jordan, Brian
Kryvokhyzha, Nadiya
Parkin, Andy
Rabani, Gouher
Rotello, Vincent M.
机构
[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland
[2] Univ Massachusetts, Dept Chem, Amherst, MA 01002 USA
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1021/ol060620q
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We report the synthesis of flavin-stoppered hydrogen bonded [2] rotaxanes 1 and 2. We also report the electrochemically controllable properties of these systems in solution, and for derivative 2, as an electropolymerized thin film.
引用
收藏
页码:2297 / 2300
页数:4
相关论文
共 20 条
[1]   Electrochemically switchable hydrogen-bonded molecular shuttles [J].
Altieri, A ;
Gatti, FG ;
Kay, ER ;
Leigh, DA ;
Martel, D ;
Paolucci, F ;
Slawin, AMZ ;
Wong, JKY .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (28) :8644-8654
[2]   Remarkable positional discrimination in bistable light- and heat-switchable hydrogen-bonded molecular shuttles [J].
Altieri, A ;
Bottari, G ;
Dehez, F ;
Leigh, DA ;
Wong, JKY ;
Zerbetto, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (20) :2296-2300
[3]   New conjugated polymerizable pyrrole and 2,5-dithienylpyrrole azobenzene dyes: synthesis and spectroelectrochemical properties [J].
Audebert, P ;
Sadki, S ;
Miomandre, F ;
Hapiot, P ;
Chane-Ching, K .
NEW JOURNAL OF CHEMISTRY, 2003, 27 (05) :798-804
[4]   MODEL SYSTEMS FOR FLAVOENZYME ACTIVITY - STABILIZATION OF THE FLAVIN RADICAL-ANION THROUGH SPECIFIC HYDROGEN-BOND INTERACTIONS [J].
BREINLINGER, E ;
NIEMZ, A ;
ROTELLO, VM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5379-5380
[5]   Photoinduction of fast, reversible translational motion in a hydrogen-bonded molecular shuttle [J].
Brouwer, AM ;
Frochot, C ;
Gatti, FG ;
Leigh, DA ;
Mottier, L ;
Paolucci, F ;
Roffia, S ;
Wurpel, GWH .
SCIENCE, 2001, 291 (5511) :2124-2128
[6]  
Chia SY, 2001, ANGEW CHEM INT EDIT, V40, P2447, DOI 10.1002/1521-3773(20010702)40:13<2447::AID-ANIE2447>3.0.CO
[7]  
2-P
[8]   The electrochemically tuneable recognition properties of an electropolymerised flavin derivative [J].
Cooke, G ;
Garety, J ;
Mabruk, S ;
Rotello, V ;
Surpateanu, G ;
Woisel, P .
CHEMICAL COMMUNICATIONS, 2004, (23) :2722-2723
[9]   Electrochemical and photochemical control of host-guest complexation at surfaces [J].
Cooke, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (40) :4860-4870
[10]  
Cosnier S, 1998, ELECTROANAL, V10, P521, DOI 10.1002/(SICI)1521-4109(199807)10:8<521::AID-ELAN521>3.3.CO