Catalysis for fine chemicals: towards specificity with polyphasic media

被引：23

作者：

Besson, M ^{[1
]}

Bonnet, MC ^{[1
]}

Gallezot, P ^{[1
]}

Tkatchenko, I ^{[1
]}

Tuel, A ^{[1
]}

机构：

[1] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France

来源：

CATALYSIS TODAY | 1999年 / 51卷 / 3-4期

关键词：

review; chemoselectivity; regioselectivity; diastereoselectivity; fine chemicals;

D O I：

10.1016/S0920-5861(99)00040-1

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Three examples of the work undertaken at the Institut de Recherches sur la Catalyse for the selective preparation of fine chemicals in polyphasic media are presented and discussed: 1. diastereoselective hydrogenation of 1,2-disubstituted arenes to cyclohexyl derivatives, 2. chemoselective oxidation of anilines, and 3. regioselective alkoxycarbonylation of styrene derivatives to 2-arylpropionic eaters. Factors influencing the selectivity of these reactions are discussed in the light of concepts from molecular chemistry. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：547 / 560

页数：14

共 33 条

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