One-pot synthesis of gold nanoparticle/molybdenum cluster/graphene oxide nanocomposite and its photocatalytic activity

被引:82
作者
Barras, Alexandre [1 ]
Das, Manash R. [2 ]
Devarapalli, Rami Reddy [3 ]
Shelke, Manjusha V. [3 ]
Cordier, Stephane [4 ]
Szunerits, Sabine [1 ]
Boukherroub, Rabah [1 ]
机构
[1] Univ Lille 1, IRI, CNRS, USR 3078, F-59658 Villeneuve Dascq, France
[2] NE Inst Sci & Technol, Div Mat Sci, CSIR, Jorhat 785006, Assam, India
[3] Natl Chem Lab, Phys & Mat Chemsitry Div, CSIR, Pune 411008, Maharashtra, India
[4] Univ Rennes 1, Inst Sci Chim Rennes, Equipe Chim Solide & Mat, CNRS,UR1 6226, F-35042 Rennes, France
关键词
Mo6Br8(N-3)(6)](2-)cluster; Graphene oxide; Gold nanoparticles; Nanohybrid; Rhodamine B; Photodegradation; Visible light; GRAPHENE; REDUCTION; SHEETS; DYES;
D O I
10.1016/j.apcatb.2012.11.017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The paper reports on a facile one-pot synthesis of a tri-component gold nanoparticle/molybdenum cluster/graphene oxide (AuNPs@Mo-GO) nanohybrid composite. The synthetic methodology consists on direct UV irradiation of an aqueous solution containing graphene oxide (GO), Na-2[Mo6Br8(N-3)(6)], HAuCl4 center dot 3H(2)O and isopropanol at room temperature in air using a UV fiber lamp. The composite material exhibits very high photocatalytic activity for the degradation of rhodamine B under visible light irradation. The resulting nanohybrid material was characterized using Raman spectroscopy, UV-vis spectrometry, transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:270 / 276
页数:7
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