[P6Se12]4-:: A phosphorus-rich selenophosphate with low-valent P centers

被引：26

作者：

Chung, I ^{[1
]}

Karst, AL ^{[1
]}

Weliky, DP ^{[1
]}

Kanatzidis, MG ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 07期

关键词：

D O I：

10.1021/ic0601135

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12](4-) anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally p(2+) and P4+ centers. The synthesis of Rb(4)P(6)Sel(2) was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.

引用

页码：2785 / 2787

页数：3

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