Selective Hydrogen Production from Methanol with a Defined Iron Pincer Catalyst under Mild Conditions

被引：294

作者：

Alberico, Elisabetta ^{[1
,2
]}

Sponholz, Peter ^{[1
]}

Cordes, Christoph ^{[1
]}

Nielsen, Martin ^{[1
]}

Drexler, Hans-Joachim ^{[1
]}

Baumann, Wolfgang ^{[1
]}

Junge, Henrik ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany

[2] CNR, Ist Chim Biomol, Sassari, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 52期

关键词：

homogeneous catalysis; hydrogen; iron catalysts; methanol; renewable energy; LIQUID-PHASE DEHYDROGENATION; HOMOGENEOUS RUTHENIUM; CARBON-DIOXIDE; SECONDARY ALCOHOLS; COBALT COMPLEXES; FORMIC-ACID; LIGANDS; KETONES; OSMIUM; BASE;

D O I：

10.1002/anie.201307224

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecularly well-defined iron pincer complexes promote the aqueous-phase reforming of methanol to carbon dioxide and hydrogen, which is of interest in the context of a methanol and hydrogen economy. For the first time, the use of earth-abundant iron complexes under mild conditions for efficient hydrogen generation from alcohols is demonstrated.

引用

页码：14162 / 14166

页数：5

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