Solid-state reactions of mercury with pure noble metals -: Part 2.: Mercury-iridium system

被引：9

作者：

Fertonani, FL ^{[1
]}

Milaré, E ^{[1
]}

Benedetti, AV ^{[1
]}

Ionashiro, M ^{[1
]}

机构：

[1] Univ Estadual Paulista, Inst Quim, BR-14801970 Sao Paulo, Brazil

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2002年 / 67卷 / 02期

基金：

巴西圣保罗研究基金会;

关键词：

cyclic voltammetry; iridium; mercury; SEM; TG; X-ray diffraction;

D O I：

10.1023/A:1013943623673

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermogravimetry, cyclic voltammetry and other analytical techniques were used to study the reactions of mercury with pure iridium. The results allowed to suggest when subjected to heat or anodic stripping voltammetry an electrodeposited mercury film reacts with Ir substrate and at least three mass loss steps and three peaks appear in the mercury desorption process. The first two were attributed to Hg(0) species removal like a mercury bulk and a mercury monolayer. The last can be ascribed to the mercury removal from a solid solution with iridium.

引用

页码：403 / 409

页数：7

共 13 条

[1]

BARLOW M, 1969, Z METALLKD, V60, P292

[2] CONTRIBUTION TO THE STUDY OF THE REACTION OF MERCURY WITH PLATINUM AND A PLATINUM-IRIDIUM ALLOY [J].

FERTONANI, FL ;

BENEDETTI, AV ;

IONASHIRO, M .

THERMOCHIMICA ACTA, 1995, 265 :151-161

[3]

FERTONANI FL, 1996, P 12 C IB 9 ENC VEN, P416

[4]

FERTONANI FL, 1999, THIN SOLID FILMS, V1, P341

[5]

*INT CTR DIFFR DAT, 1988, PDF2 INT CTR DIFFR D

[6] ALLOYING IN PLATINUM-BASED CATALYSTS FOR GASOLINE REFORMING - A GENERAL STRUCTURAL PROPOSAL [J].

JOYNER, RW ;

SHPIRO, ES .

CATALYSIS LETTERS, 1991, 9 (3-4) :239-244

[7] DEPOSITION AND STRIPPING PROPERTIES OF MERCURY ON IRIDIUM ELECTRODES [J].

KOUNAVES, SP ;

BUFFLE, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (12) :2495-2498

[8] AN IRIDIUM-BASED MERCURY-FILM ELECTRODE .1. SELECTION OF SUBSTRATE AND PREPARATION [J].

KOUNAVES, SP ;

BUFFLE, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 216 (1-2) :53-69

[9] Contribution to the study of the solid-state reaction of mercury with pure rhodium [J].

Milaré, E ;

Fertonani, FL ;

Benedetti, AV ;

Ionashiro, M .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 59 (03) :617-624

[10]

MILARE E, 1998, P 13 C SOC IB EL VIN, P140

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