Rational catalyst design via imprinted nanostructured materials

被引:225
作者
Davis, ME
Katz, A
Ahmad, WR
机构
[1] Chemical Engineering, California Institute of Technology, Pasadena
关键词
D O I
10.1021/cm960019u
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Progress on the use of imprinting (templating) for the synthesis of nanostructured catalysts is reviewed. In the context of providing a foundation for synthetic mimics, the basic principles of enzyme catalysis are enumerated. With these paradigms in mind, catalytic antibodies, imprinted polymers, imprinted amorphous metal oxides, and zeolites are discussed With respect to their preparation procedures and catalytic properties. These synthetic catalysts ape contrasted to one another in order to highlight the advantages and disadvantages of each system. Suggestions for future Work on preparing enzyme-mimicking materials by imprinting are provided.
引用
收藏
页码:1820 / 1839
页数:20
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