Optimization of alkaline earth metal oxide and hydroxide catalysts for base-catalyzed reactions

被引：145

作者：

Corma, A ^{[1
]}

Iborra, S ^{[1
]}

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46023, Spain

来源：

ADVANCES IN CATALYSIS, VOL 49 | 2006年 / 49卷

关键词：

D O I：

10.1016/S0360-0564(05)49004-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review is a summary of the work done and potential opportunities for inexpensive and easily accessible base catalysts, such as alkaline earth metal oxides and hydroxides, as well as alkali metals and oxides supported on alkaline earth metal oxides. Preparation methods of these materials, as well as characterization of basic sites are reported. An extensive review of their catalytic applications for a variety of organic transformations including isomerization, carbon-carbon and carbon-oxygen bond formation, and hydrogen transfer reactions is presented.

引用

页码：239 / 302

页数：64

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