A new architecture in lithium amide chemistry: Synthesis of [{(c-C5H9)N(H)}(12)(O)Li-14], a cage molecule containing a salt-like, distorted, face-centred cube of lithium cations

被引：22

作者：

Clegg, W

Horsburgh, L

Dennison, PR

Mckenzie, FM

Mulvey, RE

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,LANARK,SCOTLAND

[2] UNIV NEWCASTLE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 09期

关键词：

D O I：

10.1039/cc9960001065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesised in the presence of trace quantities of water, which can account for its central oxo anion, the tetradecalithium title compound represents a rare three-dimensional, high-oligomeric cage arrangement in an area generally populated by pseudo-two-dimensional ring and ladder structures.

引用

收藏

页码：1065 / 1066

页数：2

相关论文

共 13 条

[1]

Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31

[2] DILITHIATION OF A PRIMARY AMINE - SYNTHESIS AND STRUCTURE OF [(ALPHA-NAPHTHYL-NLI2)10(ET2O)6].ET2O, A PARAMAGNETIC LI20 AGGREGATE [J].

ARMSTRONG, DR ;

BARR, D ;

CLEGG, W ;

DRAKE, SR ;

SINGER, RJ ;

SNAITH, R ;

STALKE, D ;

WRIGHT, DS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (12) :1707-1709

[3]

ARMSTRONG DR, 1991, ANGEW CHEM, V104, P1702

[4] DILITHIATED SALEN COMPLEXES - CHIRAL [(SALEN)LI-2-CENTER-DOT-HMPA](2) AND DELIBERATE PARTIAL HYDROLYSIS TO GIVE [(SALEN)LI-2](3)CENTER-DOT-LI2O-CENTER-DOT-2TMEN-CENTER-DOT-H2O [H(2)SALEN=N,N'-ETHYLENEBIS(SALICYLIDENEIMINE), HMPA=HEXAMETHYLPHOSPHORAMIDE, TMEN=TETRAMETHYLETHYLENEDIAMINE] [J].

BALL, SC ;

CRAGGHINE, I ;

DAVIDSON, MG ;

DAVIES, RP ;

LOPEZSOLERA, MI ;

RAITHBY, PR ;

REED, D ;

SNAITH, R ;

VOGL, EM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (20) :2147-2149

[5] CRYSTAL-STRUCTURE OF LITHIUM DIISOPROPYLAMIDE (LDA) - AN INFINITE HELICAL ARRANGEMENT COMPOSED OF NEAR-LINEAR N-LI-N UNITS WITH 4 UNITS PER TURN OF HELIX [J].

BARNETT, NDR ;

MULVEY, RE ;

CLEGG, W ;

ONEIL, PA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (21) :8187-8188

[6] DISASSEMBLING LITHIUM AMIDE LADDER STRUCTURES - STRUCTURAL ELUCIDATION OF THE LITHIUM ANILIDE SOLVATE [(PHN(H)LI)6-CENTER-DOT-8THF], A MODEL INTERMEDIATE EN-ROUTE TO FORMING TETRA-SOLVATED RING DIMERS [J].

CLEGG, W ;

HORSBURGH, L ;

MACKENZIE, FM ;

MULVEY, RE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) :2011-2012

[7] SYNTHESES AND STRUCTURAL STUDIES OF [2-(6-METHYL)PYRIDYL]- AND (8-QUINOLYL)-TRIMETHYLSILYLAMIDO-LITHIUM COMPLEXES [J].

ENGELHARDT, LM ;

JACOBSEN, GE ;

JUNK, PC ;

RASTON, CL ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (04) :1011-1020

[8] SOLID-STATE AND SOLUTION STRUCTURE OF DILITHIUM TRIMETHYL((PHENYLSULFONYL)METHYL)SILANE, A TRUE DILITHIOMETHANE DERIVATIVE [J].

GAIS, HJ ;

VOLLHARDT, J ;

GUNTHER, H ;

MOSKAU, D ;

LINDNER, HJ ;

BRAUN, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (03) :978-980

[9] STRUCTURES OF ORGANONITROGEN LITHIUM COMPOUNDS - RECENT PATTERNS AND PERSPECTIVES IN ORGANOLITHIUM CHEMISTRY [J].

GREGORY, K ;

SCHLEYER, PV ;

SNAITH, R .

ADVANCES IN INORGANIC CHEMISTRY, 1991, 37 :47-142

[10]

HENDERSON KW, 1994, J AM CHEM SOC, V116, P1077