Separation of E-Z isomeric macrocyclic spermine alkaloids of Verbascum pseudonobile and Verbascum phoeniceum and of their derivatives using thin-layer chromatography

被引:14
作者
Drandarov, K [1 ]
Hais, IM [1 ]
机构
[1] CHARLES UNIV,FAC PHARM,DEPT BIOCHEM SCI,CR-50005 HRADEC KRALOVE,CZECH REPUBLIC
关键词
Verbascum; alkaloids; spermine alkaloids;
D O I
10.1016/0021-9673(95)01066-1
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Twelve E-Z isomeric pairs of Verbascum pseudonobile Stoj. et Stef. and Verbascum phoeniceum L. (Scrophulariaceae) macrocyclic spermine alkaloids and of related compounds and six related dihydro derivatives were studied by TLC on silica in nine systems and on alumina in four systems. In most cases the Z isomers exhibited higher retention than their E counterparts, Four E-Z isomeric pairs of cinnamic acid amides were studied for comparison.
引用
收藏
页码:416 / 423
页数:8
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