Preparation of cyclic carbonates from alkadienols, CO2, and aryl or vinylic halides catalyzed by a palladium complex

被引：42

作者：

Uemura, K ^{[1
]}

Shiraishi, D ^{[1
]}

Noziri, M ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Chem Mat, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1999年 / 72卷 / 05期

关键词：

D O I：

10.1246/bcsj.72.1063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel three-component reaction of alkadienol, CO2, and aryl or vinylic halide gives a vinyl group-substituted cyclic carbonate in one pot in the presence of a catalytic amount of a palladium complex. 2,3-Alkadienol affords five-membered ring carbonate in good yield, while 3,4-alkadienol effects the six-membered one successfully. 2,4-Alkadienol also takes part in this reaction to provide five-membered ring carbonate. A reaction pathway involving a pi-allylic palladium species as an intermediate has been presumed.

引用

页码：1063 / 1069

页数：7

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