Efficient and selective nickel-catalyzed addition of H-P(O) and H-S bonds to alkynes

被引：236

作者：

Han, LB ^{[1
]}

Zhang, C ^{[1
]}

Yazawa, H ^{[1
]}

Shimada, S ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 16期

关键词：

D O I：

10.1021/ja0494297

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cheap nickel catalysts are more reactive than the corresponding noble metal catalysts in the catalytic additions of a variety of P(O)-H bonds and an S-H bond to alkynes, affording regio- and stereoselectively both the Markovnikov and the anti-Markovnikov adducts, respectively, in high yields. A related five-coordinate hydrido nickel complex in the catalysis is successfully isolated, which can react readily with an alkyne to give the addition products. Copyright © 2003 American Chemical Society.

引用

页码：5080 / 5081

页数：2

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